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Anion-Binding Catalysis
Explores the potential of new types of anion-binding catalysts to solve challenging synthetic problems Anion-Binding Catalysis introduces readers to the use of anion-binding processes in catalytic chemical activation, exploring how this approach can contribute to the future design of novel synthetic transformations.Featuring contributions by world-renowned scientists in the field, this authoritative volume describes the structure, properties, and catalytic applications of anions as well as synthetic applications and practical analytical methods. In-depth chapters are organized by type of catalyst rather than reaction type, providing readers with an accessible overview of the existing classes of effective catalysts.The authors discuss the use of halogens as counteranions, the combination of (thio)urea and squaramide-based anion-binding with other types of organocatalysis, anion-binding catalysis by pnictogen and tetrel bonding, nucleophilic co-catalysis, anion-binding catalysis by pnictogen and tetrel bonding, and more.Helping readers appreciate and evaluate the potential of anion-binding catalysis, this timely book: Illustrates the historical development, activation mode, and importance of anion-binding in chemical catalysis Explains the analytic methods used to determine the anion-binding affinity of the catalysts Describes catalytic and synthetic applications of common NH- and OH-based hydrogen-donor catalysts as well as C-H triazole/triazolium catalysts Covers amino-catalysis involving enamine, dienamine, or iminium activation approaches Discusses new trends in the field of anion-binding catalysis, such as the combination of anion-binding with other types of catalysis Presenting the current state of the field as well as the synthetic potential of anion-binding catalysis in future, Anion-Binding Catalysis is essential reading for researchers in both academia and industry involved in organic synthesis, homogeneous catalysis, and pharmaceutical chemistry.
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Cation or anion?
A cation is a positively charged ion, while an anion is a negatively charged ion. Cations are formed when an atom loses electrons, resulting in a net positive charge, while anions are formed when an atom gains electrons, resulting in a net negative charge. The charge of a cation is indicated by a superscript plus sign (+), while the charge of an anion is indicated by a superscript minus sign (-).
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Which anion is formed?
The anion formed is chloride (Cl-). When sodium chloride (NaCl) dissolves in water, it dissociates into sodium cations (Na+) and chloride anions (Cl-). The chloride anion carries a negative charge and is attracted to the positive end of the water molecule, forming a hydrated chloride ion.
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What is the anion of potassium carbonate?
The anion of potassium carbonate is the carbonate ion (CO3^2-). This ion is composed of one carbon atom and three oxygen atoms, and it carries a 2- charge. When combined with a potassium cation (K+), it forms the compound potassium carbonate (K2CO3).
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Is the acid conjugate to the anion a weak acid if the anion is a good leaving group?
Yes, if the anion is a good leaving group, then the acid conjugate to the anion is likely to be a weak acid. This is because a good leaving group is typically stable and less likely to hold onto its proton, making the corresponding acid less likely to donate its proton. Therefore, the acid conjugate to the anion would be weak in terms of its ability to donate a proton in a chemical reaction.
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How do you distinguish a cation from an anion?
Cations are positively charged ions, while anions are negatively charged ions. Cations are formed when an atom loses one or more electrons, resulting in a net positive charge. Anions are formed when an atom gains one or more electrons, resulting in a net negative charge. One way to distinguish between cations and anions is to observe their behavior in a solution: cations are attracted to the negative electrode (cathode) in electrolysis, while anions are attracted to the positive electrode (anode). Additionally, cations are usually smaller in size than their parent atoms, while anions are larger.
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How is the sodium cation connected to a chloride anion?
The sodium cation is connected to a chloride anion through ionic bonding. In this type of bonding, the sodium atom loses an electron to become a positively charged cation, while the chloride atom gains an electron to become a negatively charged anion. The opposite charges of the sodium cation and chloride anion attract each other, forming a strong bond between the two ions. This ionic bond creates a stable compound known as sodium chloride, or table salt.
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How is the reduction of the dichromate anion carried out?
The reduction of the dichromate anion is typically carried out using a reducing agent such as sulfur dioxide, iron(II) salts, or thiosulfate. These reducing agents donate electrons to the dichromate anion, causing it to be reduced to chromium(III) ions. The reaction is usually carried out in an acidic solution to provide the necessary conditions for the reduction to occur efficiently.
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Why is there no KSO4 molecule? Why is it an anion?
There is no KSO4 molecule because potassium (K) is a metal and sulfate (SO4) is a polyatomic ion. When potassium combines with sulfate, it forms the ionic compound potassium sulfate (K2SO4), in which potassium loses an electron to become a positively charged ion (K+) and sulfate gains two electrons to become a negatively charged ion (SO4^2-). This ionic bond between the positively charged potassium ion and the negatively charged sulfate ion results in the formation of an anion rather than a molecule.
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